Titanium Materials

Titanium Materials

Titanium Materials
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  • Titanium Materials

Titanium MaterialsGlobal Sourcing for Engineering & Procurement 

 

1. Product Positioning and Application Scope

Forms covered: Plate and coil (ASTM B265), bars and billets (ASTM B348), seamless and heat-exchanger tubing (ASTM B338, ASTM B861), welded pipe (ASTM B862), butt-welded fittings (ASTM B363), forgings (ASTM B381), welding wire and wire rod (ASTM B863), Ti-steel clad plate (explosive or roll-bonded per project specification).

Common grades: CP titanium Grades 14; alloys Grade 5 (Ti-6Al-4V), Grade 23 (ELI), Grades 7 and 16 (Pd-modified for oxidizing media), Grade 9 (Ti-3Al-2.5V for thin-wall tubing), Grade 12 (Ti-0.3Mo-0.8Ni for crevice/sea-water resistance), and other engineering grades on request.

Typical industries: Seawater and brine systems, offshore and offshore wind, chemical and chlor-alkali, pulp & paper bleaching, power plant condensers and exchangers, salt chemistry and wet-chlorine services, pharmaceutical and food (media-side components), aerospace structures and thermal parts, medical devices and implants (if required per ASTM F67, ASTM F136 or ISO 5832 series).

Boundary note: Typical long-term service temperature for titanium is about 315 °C subject to grade and environment; strongly reducing acids and severe crevice conditions require dedicated compatibility checks.

 

2. Standards Matrix (for ordering and acceptance)

ASTM/ASME: ASTM B265 (plate/coil), ASTM B348 (bars/billets), ASTM B338 (tubes for condensers/heat exchangers), ASTM B861 (general seamless pipe), ASTM B862 (general welded pipe), ASTM B363 (butt-welded fittings), ASTM B381 (forgings), ASTM B863 (wire/welding wire). ASME counterparts carry the SB-prefix. Note: ASTM B337 has been replaced by B861/B862.

International/European: EN 10204 (3.1/3.2 certificates), PED 2014/68/EU (when used in pressure equipment), NACE MR0175/ISO 15156 (sour-service statement as applicable), ISO 5832 (medical), and project-specific AMS or client specifications as required.

Japanese (by agreement): JIS H 4600 (sheet/strip/plate), JIS H 4601 (bars and wire). For tubing, use ASTM B338/B861/B862.

 

3. ScenarioMaterialStandardSize Mapping (buyer shortcut)

1. Seawater cooling and offshore circulation

Materials: Grade 2 or Grade 12; for highly oxidizing spots or disinfectant-rich zones use Grade 7 or Grade 16.

Standards & forms: ASTM B338 for exchanger tubes; ASTM B861/B862 for general pipe; ASTM B363 for fittings; ASTM B381 for flanges/rings.

Typical sizes: B338 tubes OD 12.725.4 mm, WT 0.52.0 mm, length 612 m; general pipe up to OD 21.3610 mm (project-specific).

2. Chemical, chlor-alkali, wet chlorine and chlorine-dioxide services

Materials: Grade 7 (Ti-0.15Pd), Grade 16 (Ti-0.05Pd); Grade 12 for cost-effective options.

Standards & forms: B265 plates/coils; B338 tubes; B863 filler/wire.

Typical sizes: Plates 225 mm thick, 10002000 mm wide; tubes OD 12.738.1 mm.

3. Power plant condensers and heat exchangers

Materials: Grade 2, Grade 12; upgrade to Grade 7/16 for specific corrosion zones.

Standards & forms: B338 tubes; B363/B381 for nozzles, headers and manifolds.

Typical sizes: OD 12.725.4 mm, WT 0.51.65 mm, U-bend or straight, length 618 m (per unit design).

4. Thin-wall high-pressure and instrument tubing

Materials: Grade 9 (Ti-3Al-2.5V).

Standards & forms: ASTM B338, ASTM B861.

Typical sizes: OD 625 mm, WT 0.52.0 mm.

5. High-strength lightweight structures and fastener blanks

Materials: Grade 5 (Ti-6Al-4V), Grade 23 (ELI).

Standards & forms: B348 bars, B381 forgings; near-net-shape forgings per drawing.

Typical sizes: Bars Ø 8200 mm; forgings per drawing.

6. Media-side hygienic components in pharma/food

Materials: Grade 2, Grade 12; polishing or electropolishing as required.

Standards & forms: B265 plates/coils; B338 tubes; documentation per client hygiene protocols.

7. Medical and implant (when applicable)

Materials: Grade 4, Grade 23 (ELI).

Standards & forms: ASTM F67, ASTM F136, ISO 5832 series; surface and purity per medical requirements.

Typical sizes: Bars Ø 660 mm common.

 

4. Size Range and Tolerances (per standards)

Plate/coil (ASTM B265): Thickness 0.560 mm (heavier via forging/rolling), width 10002000 mm, length 212 m; dimensional/flatness per B265.

Bars (ASTM B348): Ø 6300 mm, length 26 m; dimensions/straightness per B348.

Exchanger/Condenser tubes (ASTM B338): OD 1238 mm, WT 0.52.0 mm, length 618 m; OD/WT/ovality/straightness per B338.

General seamless/welded pipe (ASTM B861/B862): OD 21.3610 mm, length 612 m; tolerances per respective clauses.

Fittings/forgings (ASTM B363/B381): Dimensions per drawing or ASME B16.9/B16.5 geometry; NDE and tolerances per standards/order.

Wire/welding wire (ASTM B863): Ø 1.24.0 mm typical; chemistry, mechanicals and tolerances per B863.

 

5. Manufacturing Flow and Key Controls

Melting: VAR or VIM+VAR for industrial grades; medical/aerospace per client route.

Deformation/heat treatment: Hot-rolled/forged solution or recrystallization anneal pickling/passivation; strict control of O/N/H for Grades 5/23.

Welding/forming: Inert-gas shielding; control of cleanliness and hydrogen pickup; thin-wall bends within thinning/ovality windows.

Surface/cleanliness: Remove free iron/contamination; critical exchanger IDs available with low-roughness and cleanliness reports.

 

6. Quality Verification and Documentation

Chemistry and gas elements: Verify O/N/H per grade limits.

Mechanical properties: YS/UTS/Elongation/Hardness; optional low-temperature or creep testing.

NDE: Hydro or pneumatic testing of each tube; helium leak as required; UT on forgings/rings.

Corrosion/compatibility: Added per project (e.g., actual seawater chemistry); supply ID cleanliness data if required.

Documents: EN 10204 3.1 or 3.2 CMTRs, heat-treat charts, NDE reports, PED/NACE statements as applicable.

 

7. Supply Forms and Packaging

Forms: Plates/coils, bars and rings, seamless/welded pipes, exchanger U-tubes, butt-welded fittings, near-net forgings, welding wire.

Packaging: End caps, moisture protection and desiccants, scratch-free separation; segregate from carbon steel to avoid galvanic issues/contamination.

Marking: Grade, condition, size, heat/lot, net weight, standard/edition, and traceable QR code if needed.

 

8. Ordering Checklist (ready to copy)

1. Standards/editions, e.g., ASTM B338-2024,  ASTM B265-2023.

2. Grades/condition, e.g., Grade 2 Annealed, Grade 7 Annealed, Grade 5 Annealed, Grade 23 ELI.

3. Form/size: Pipe OD × WT × Length, Plate Thickness × Width × Length; state tolerance class.

4. Tests: Hydro/pneumatic/helium coverage, UT share, gas elements and cleanliness.

5. Service data: Cl, oxidizers, temperature, velocity, allowable ΔP and design life.

6. Docs/witness: EN 10204 3.1/3.2, TPI as needed, PED/NACE statements.

7. Surface/pack: ID/OD condition, roughness target, unit/pallet packing and transport limits.

 

9. Grade Selection Guide (quick path)

Seawater/brine: Grade 2 or Grade 12; upgrade to Grade 7/16 at oxidizing hotspots.

Strong oxidizing chemicals (wet chlorine/ClO): Prefer Grade 7/16.

Thin-wall forming/high-pressure: Grade 9.

High strength/lightweight: Grade 5; higher toughness use Grade 23 (ELI).

Exchangers/condensers: B338 tubing in Grade 2/12.

Medical/implant: Order to ASTM F67, ASTM F136 or ISO 5832 as specified.

 

10. Procurement, Installation and O&M Risk Notes

Standard misuse: Do not order to obsolete ASTM B337; use B861/B862 for general pipe.

Galvanic corrosion: Insulating kits and CP coordination at TiCS/Cu joints; avoid crevices and stagnant zones.

Crevice control: Gasket details, supports and fouling-prone areas must be designed and maintained to eliminate crevices.

Hydrogen pickup: Control pickling/welding practice; deliver within grade H-content limits.

Temperature envelope: Evaluate long-term limits per grade; dry chlorine at elevated temperature and similar media require caution.

 

11. Representative Line Items (copy-ready)

Exchanger straight tubes:

Tube, ASTM B338, Grade 2, OD 19.05 mm × WT 1.24 mm × L 9.14 m, annealed; hydro or pneumatic test each; ID/OD cleanliness records; EN 10204 3.1 CMTR.

Condenser U-tubes:

U-Tube, ASTM B338, Grade 12, OD 25.4 mm × WT 1.65 mm, annealed; bend thinning/ovality per drawing; brush-clean and cap both ends; CMTR 3.1.

Seawater branch flanges/rings:

Forgings, ASTM B381, Grade 7, flange blanks and rings per drawing; 100% UT; pickled and passivated; EN 10204 3.1.

Chemical column internals (plate):

Plate, ASTM B265, Grade 16, 6 mm × 1500 mm × 6000 mm; annealed + pickled; flatness per B265; CMTR 3.1.

Thin-wall instrument tubing:

Tube, ASTM B338, Grade 9, OD 12 mm × WT 1.0 mm × L 6 m; annealed; OD/WT tolerances per B338; pneumatic test each; CMTR 3.1.

 

12. Representative Global Producers (alphabetical, examples)

Alleima (titanium heat-exchanger tubing).

ATI (plate, bar and tubular titanium).

BAOTI Group (plate, bar, tube and forgings).

Fine Tubes / Superior Tube (AMETEK; precision Ti tubing).

Kobe Steel (titanium products and tubing).

Nippon Steel Titanium (sheet/coil and surface-engineered Ti).

Perryman Company (bar/rod and wire).

TIMET (Titanium Metals Corp.; plate, bar, tube and forgings).

Western Superconducting / Western Metal Materials (bars, forgings and tubes).

Note: Melting route, size capability and QA windows vary by producer; orders follow mill datasheets and contract terms. Certain grades/regions may be subject to export controls and compliance requirements.

 

 

 

Titanium Materials (Tubes, Plates, Fittings & Flanges) Technical Specifications

 

1) Definition & Scope

Titanium includes CP-Ti and titanium alloys (α/near-α/α+β/β).

Supply forms: tubes/pipes, sheets/plates/coils, bars/wires/forgings, fittings & flanges.

Industries: seawater/brine, chemical process (corrosive media), power condensing & HX, aerospace, medical & ultra-clean systems.

 

 

2) Standards (incl. China GB; grouped by product)

Tubes/Pipes: ASTM B338 (HX/condenser tubing), ASTM B861 (seamless pipe), ASTM B862 (welded pipe), GB/T 3624 (seamless), GB/T 3625 (cold-worked or welded-rolled tubes).

Sheets/Plates: ASTM B265 / ASME SB265, GB/T 3621.

Bars/Wires/Forgings: ASTM B348 (bars/billets), ASTM B863 (wire), ASTM B381 (forgings).

Fittings/Flanges: ASTM B363 (BW fittings), ASME B16.9/B16.5/B16.47 (geometry & ratings; material per B381).

Medical/Aerospace (if applicable): ASTM F67 / F136, ISO 5832-2/-3/-11; welding per AWS D17.1 / ISO 15614-5.

MTC: EN 10204 3.1/3.2; add PED/ASME/Classification Society clauses if required.

 

 

3) Grades & UNS (key traits)

CP-Ti: Gr.1 (R50250) best formability; Gr.2 (R50400) balanced & common; Gr.3/Gr.4 higher strength.

Pd-bearing corrosion-resistant: Gr.7/Gr.11/Gr.16/Gr.17 for improved crevice/reducing media resistance.

Elevated temperature/reducing brines: Gr.12 (R53400) outperforms Gr.2.

α+β structural: Gr.5 (R56400), Gr.23 ELI (R56401); thin-wall aerospace tubing Gr.9 (R56320).

Temperature guidance: CP-Ti ~315 °C; Gr.5/Gr.9 ~400 °C unless special near-α alloys are justified.

 

 

4) Dimensions & Tolerances (use code limits; typical envelopes)

B338 tubing: OD 638 mm, WT 0.52.0 mm, L 312 m; OD/WT/straightness/ovality per B338.

B861/B862 pipes: OD 25610 mm, WT 225 mm, L 612 m; tolerances per B861/B862.

B265/GB 3621 plates: t 0.560 mm, W 2000 mm, L 600012000 mm; thickness/flatness per code.

B348 bars: dia 6400 mm, L 26 m; straightness/ovality per code.

B381 forgings: rings/disks/shafts & flange blanks; UT level per PO.

U-bends: geometry R, a, lg, Smin, flattening/ thinning per TEMA RCB-2.31.

 

 

5) Manufacturing & KCP

VAR/EB forging inspection defect removal

Seamless: hot pierce/extrude cold pilger/draw with inter-anneal size/straighten.

Welded: coil-form GTAW/laser (full inert shielding) PWHT/anneal size/straighten.

Sheets/plates: hot-roll (cold-roll) anneal remove scale & alpha-case level/trim.

Fittings/flanges: free/die forging or ring-rolling HT (N/T/Q+T or solution) machining NDE.

Cleaning: controlled HNO₃–HF pickling window; de-hydrogenation/stress-relief as needed.

Welding: back-purge, cleanliness, heat-input/interpass control, color acceptance (silver/straw OK; blue/black NG).

Contamination control: segregated tooling/media.

Machining safety: Class-D extinguishers; manage fines/chips as combustible metal.

 

 

6) QA/QC (ITP outline)

Chemistry + O/N/H; macro & UT on ingots/billets; mechanicals (tension/hardness, impact/creep if required); dimensional & geometry;

NDE: B338 ECT/UT, B861/B862 full-length UT/ECT, B381 100% UT (Level II recommended);

Pressure tests: hydro/pneumatic per code/drawing;

Surface & alpha-case removal records;

Docs: EN 10204 3.1/3.2, HT charts, NDE/pressure, PMI, WPS/PQR, cleaning & color logs; third-party (TÜV/SGS/LR/BV/DNV) on demand.

 

 

7) Quick Service-to-Grade Mapping

Seawater/brine HX & CW: Gr.2 (economic) or Gr.16/Gr.7 where crevice/CP risks exist.

Hot brine/reducing media: Gr.12.

Strong oxidizers (HNO): Gr.2/Gr.7.

Structural & lightweight: Gr.5, Gr.23 for low-interstitial/medical.

Thin-wall aero tubing: Gr.9.

Not recommended: HF/strongly reducing fluorides, dry chlorine at elevated T.

 

 

8) Construction & Risk Controls

Galvanic isolation vs. Cu/CS in seawater (insulating gaskets/sleeves & supports);

Gasket choice: PTFE-based, avoid bare graphite contact;

Post-weld: thorough rinse/dry; de-hydrogenation/stress-relief as required;

Weld color acceptance: silver/straw accept; blue/black reject;

Cleanliness: oil-free/particle-controlled for HX/UHP/medical;

Cathodic protection potential control to limit H-uptake;

Fire safety in machining: Class-D extinguishers;

Packaging: chloride-free materials, end caps + desiccant, maritime salt-spray protection.

 

 

9) RFQ/PO Checklist

Standard + grade (e.g., ASTM B338 Gr.2, ASTM B861 Gr.12, ASTM B363 WP-Gr.2, ASTM B381 F-Gr.2);

Size & tolerances (tube OD × WT × L, plate t × W × L; straightness/ovality/flatness class);

Supply & inner surface (AP/BA/EP);

Exams & docs (hydro/air-leak, ECT/UT/RT, PMI, alpha-case records, EN 10204 3.1/3.2, 3rd-party);

Welding & assembly (WPS/PQR, back-purge, color acceptance);

Service data (Cl/pH, T/P, corrosion allowance/allowable rate, design life);

Packaging & ID (caps/desiccant/film, barcode/traceability, handling & marine protection).

 

 

10) Major Global Producers & Processors (illustrative; verify scope & certs)

Integrated melt/ingot/plate-bar: ATI Specialty Alloys & Components (US), BAOTI (CN), Howmet Aerospace / Arconic-RTI (US, forgings/rings), KOBE STEEL (JP), NIPPON STEEL (JP, TranTixxii sheets), Osaka Titanium Technologies (JP), TIMET (US, PCC group), Toho Titanium (JP), UKTMP (KZ), VSMPO-AVISMA (RU), Western Superconducting Technologies (CN).

Tubes/HX tubing (some multi-alloy portfolios): Alleima (SE, ex-Sandvik), BAOTI (CN), Fine Tubes (UK)/Superior Tube (US), KOBELCO (JP), TIMET (US, limited).

Forgings/rings (incl. aerospace): Aubert & Duval (FR), Galperti / Melesi / Metalfar / Forgital (IT), Howmet Aerospace (US), VSMPO-AVISMA (RU), ULMA Forged Solutions (ES), Dingxiang cluster (CN).

Service centers/clusters: Baoji Titanium Valley (CN), Supra Alloys (US), NeoNickel (EU/UK), ThyssenKrupp Materials NA (US), VSMPO-Tirus (global distribution).

(Trade restrictions and certifications evolve; validate ISO 9001/14001/45001, AS9100, PED, ASME, Class approvals, and recent references before RFQ.)

 

 

11) Pitfalls & Risk List

Wrong pipe spec (use B861 not B337); mixing B862 pipe with B338 tubing;

No back-purge or color-rejected welds accepted;

Alpha-case not fully removed; excessive pickling H-uptake;

No galvanic isolation vs. Cu/CS in seawater;

Using Gr.2 in hot brine/reducing media (should be Gr.12 or Pd grades);

No MTC type, 3rd-party, or NDE level in PO;

Chloride-laden packaging, no marine protection, open-ended tubes in transit.

 

 

12) Sample Spec Lines

A (HX U-tubes): ASTM B338 Gr.2, OD 19.05 mm, WT 1.24 mm, L 9 m, U-bend per TEMA RCB-2.31 (R, lg, Smin to be validated). 100% ECT + hydro. Inner surface BA. Docs EN 10204 3.1 with hydro/ECT/PMI/pickling records.

B (Process seamless pipe): ASTM B861 Gr.12, OD 168.3 mm (NPS 6), WT 6.35 mm, L 6 m. Full-length UT. Ends BE. WPS/PQR with back-purge. Docs 3.2 (3rd-party).

C (Flange & fitting): ASTM B381 F-Gr.2 flange, ASME B16.5 Class 150 WN RF, NPS 8, RF roughness 125250 AARH; 100% UT (Level II); face protection. ASTM B363 WP-Gr.2 LR elbow 90° DN200 to match B861 pipe; acid-cleaned; Docs 3.1.

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Tsisco Industrial Ltd.
Tsisco Industrial Ltd.